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We are the only fastener manufacturer in India who are
doing high Temperature galvanizing. using Morganite Ceramic
Crucible .
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Comparison Between Conventional
Galvanizing & high Temperature Galvanizing:
In high Temperature galvanizing it is essential
to operate temperature above critical range of 480-520
C. where the rate of the attack by Zinc on Steel is very
rapid and shows a distinct peak. This serves as the
demarcation between conventional galvanizing, which is
normally carried out at 460-560 C. As the solubility of
Iron in Zinc at that high temperature is much higher
(about 0.3% compared to the preferred range of 0.1 % for
proper galvanizing.), the conventional design using
Steel Kettle is not suitable. Consequently a ceramic
lined top fired design is normally resorted to. |
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Finish as compared with conventional
Galvanizing:
In conventional galvanizing process continuous
generation of the Dross takes place due to Zinc attack
on the Steel Kettle (in addition to the normal process
of Dross formation due to immersion of Steel parts to be
galvanized. The presence of pimples and entrapped Dross
particles on the surface of the galvanized Bolts renders
the coating layer discontinuous and hence inconsistent.
The products galvanized in high temperature galvanizing
bath have a smooth matt grey finish. It will be observed
that there is no trace of lumpiness or pimples on the
surface due the absence of Zeta layer during high
Temperature Galvanizing. |
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Behavior in Preece Testing:
In an experiment it is evident that in most cases, conventional
galvanized samples have with stood 4 dips in the preece
test and failed after fifth dip. Inspite of the generally
high coating thickness, none of the samples withstood
a preece dip of 5.This implies demonstrates the absence
of uniformity of coating in conventional galvanizing.
However in high temperature galvanizing a definite correlation
is seen to exist between the coating weights and the number
of Preece dips withstood by the sample. The high temperature
galvanized samples are generally seem to have withstood
more dips for the same or lower coating thickness-which
can be explained by greater uniformity of the coating
achieved and absence of pimples.This also demonstrates
a higher level of corrosion resistance from the ,measured
coating thickness values.
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The important effect of high temperature galvanizing is
the elimination of the Sandelin phenomenon. The Sandelin
phenomenon can be interpreted based on the Kinetics,
Morphology
and thermodynamics of Galvanizing, showing that the first intermettalic compound to precipitate at 450 C during
the steel Zinc Reaction is the zeta Phase. Then the Iron
Diffusion varies from the parabolic law with low silicon
content steels to a linear independence with Sandelin steels. Since the Zeta intermetallic compound disappears
above 530 C., the first inter metallic compoundto
precipitate during the zinc steel Reaction at high
temperature is the Delta Rich Phase. Thus disappearance of Sandelin phenomenon
is established in high temperature galvanizing. |